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The epsilon class of GSTs is not present in mammals and the active-site Tyr9 crucial to the mammalian ketosteroid isomerase activity is replaced by a Ser residue, but the insect GST still displays considerable activity in the double-bond isomerization of 5-AD and 5-PD (Škerlová et al., 2020)
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Indeed, S is probably the atom most often used to directly alter the oxidation state of oxygen atoms within our cells
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